Synthesis of Polycyclic n/5/8 and n/5/5/5 Skeletons Using Rhodium- Catalyzed [5+2+1] Cycloaddition of Exocyclic-ene- vinylcyclopropanes and Carbon Monoxide

Wang, LN; Huang, ZQ; Yu, ZX

Yu, ZX (通讯作者)，Peking Univ, Coll Chem, Beijing Natl Lab Mol Sci BNLMS, Key Lab Bioorgan Chem & Mol Engn,Minist Educ, Beijing 100871, Peoples R China.

ORGANIC LETTERS, 2023; 25 (10): 1732

Abstract

A rhodium-catalyzed [5 + 2 + 1] reaction of exocyclic-ene-vinylcyclopropanes (exo-ene-VCPs) and CO has been realized to access challenging tricyclic n......

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