Challenging an old paradigm by demonstrating transition metal-like chemistry at a neutral nonmetal center

Biskup, D; Schnakenburg, G; Boeré, RT; Ferao, AE; Streubel, RK

Streubel, RK (通讯作者),Rheinische Friedrich Wilhelms Univ Bonn, Inst Organ Chem, Gerhard Domagk Str 1, D-53121 Bonn, Germany.;Ferao, AE (通讯作者),Univ Murcia, Dept Quim Organ, Fac Quim, Campus Espinardo, Murcia 30100, Spain.

NATURE COMMUNICATIONS, 2023; 14 (1):

Abstract

We describe nonmetal adducts of the phosphorus center of terminal phosphinidene complexes using classical C- and N-ligands from metal coordination che......

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